Nitrogen Generators

Membrane and PSA Nitrogen Generators Explained

January 16, 2024

I. Introduction

When it comes to onsite nitrogen generation, two prominent technologies stand out: Pressure Swing Adsorption (PSA) and Membrane Generators. Each of these technologies offers unique advantages and limitations, making it crucial to choose the right one for your specific application or industry. This article will review the technical differences between membrane and pressure swing adsorption (PSA) nitrogen generators to help you better understand this technology.

II. PSA Nitrogen Generators: A Technical Overview

2.1 What is PSA Nitrogen Generation?

Pressure swing adsorption (PSA) is a widely used nitrogen separation technique and functions on the principle of selective adsorption under pressure. It relies on solid adsorbents like activated carbon to isolate the target gas from ambient air. Each gas exhibits a characteristic adsorption rate that determines its retention by the adsorbent material within the separation vessels.

2.2 How PSA Generators Work

The nitrogen production process starts by pressurising one of the adsorption vessels with clean feed air. When high pressure is reached, carbon molecular sieves (CMS) adsorb the unwanted gases as the air flows across them, and the CMS traps these gases until it reaches saturation. The system then directs the feed air to the second vessel to start the adsorption process. The first vessel goes through the desorption phase, which involves dropping the pressure to release the unwanted gases and isolate nitrogen. The adsorption vessels are alternatively loaded to guarantee a continuous flow of nitrogen (figure 1).

Figure 1. Schematic diagram of nitrogen generation in a PSA nitrogen generator. 

III. Membrane Nitrogen Generators: A Technical Overview

3.1 What is Membrane Nitrogen Generation?

Membrane nitrogen generators are based on the principle of selective permeation and use semi-permeable membranes to separate gases. Each gas has a characteristic permeation rate determining its ability to dissolve and diffuse through a membrane. The module in which the nitrogen extraction takes place is a cylindrical bundle of hollow fibre membranes.

3.2 How do Membrane Nitrogen Generators Work?

In membrane nitrogen generators, the compressed air is fed through the hollow fibre membranes. “Fast” gases such as oxygen, carbon dioxide, and water vapour quickly permeate through the fibre walls. In contrast nitrogen, a “slower” gas, does not permeate through the fibre as easily under flowing conditions. It flows down the bore of the fibres and exits at the end of the high-pressure shell (figure 2). The separated nitrogen is collected as a high-purity product.

Figure 2. Schematic diagram of nitrogen generation in a membrane nitrogen generator.

IV. What is the difference between Membrane and PSA Nitrogen Generators?

When considering the choice between PSA and membrane nitrogen generators, it is essential to understand the differences between membrane and PSA nitrogen generation technologies. Here is a detailed comparison:

4.1 Nitrogen Purity and Quality

  • PSA Nitrogen Generators: PSA technology delivers nitrogen at the highest purity levels, often exceeding 99.99%. That is why PSA generators are the preferred choice for applications where even the slightest impurities can have significant consequences, such as in food & beverage nitrogen production.
  • Ideal for applications requiring the highest nitrogen purity levels.
  • Membrane Nitrogen Generators: Membrane generators offer good purity for a wide range of applications and have purity levels ranging up to 99.5%. However, they typically do not match the ultra-high purity levels that PSA generator systems can achieve. This makes membrane generators more suitable for applications where stringent purity requirements are not a primary concern, such as nitrogen generation for tyre filling.
  • Ideal for applications requiring high-volume nitrogen with low purity needs.

4.2 Energy Efficiency

  • PSA Nitrogen Generators: PSA nitrogen generators tend to consume more energy compared to membrane systems due to their cyclic adsorption-desorption process. The desorption phase involves purging the adsorbent with a counter-flow of nitrogen to release the captured nitrogen molecules. While this results in high-purity nitrogen, it comes at the cost of increased energy consumption.
  • Membrane Nitrogen Generators: Membrane generators are renowned for their energy efficiency. They operate based on simple diffusion through semi-permeable membranes, requiring less energy. As a result, membrane technology is a cost-effective choice for applications with a continuous, high-volume nitrogen demand.

4.3 Maintenance and Lifecycle

  • PSA Nitrogen Generators: PSA systems typically require more maintenance due to more moving parts associated with the cyclic adsorption-desorption process. Maintenance tasks may include servicing and changing valves. However, with routine maintenance, our PSA generators are expected to last over ten years or 60,000 operating hours easily.
  • Membrane Nitrogen Generators: Membrane generators have minimal maintenance needs. Since they lack moving parts and intricate adsorption mechanisms, their upkeep primarily involves routine inspections. However, the membrane’s performance will decline as it ages. Our nitrogen membranes also have an expected lifespan of over 10 years or 60,000 operating hours with regular maintenance.

4.4 Application-Specific Considerations

  • When to Choose PSA? Opt for PSA nitrogen generators when your application needs high nitrogen purity. Industries include semiconductor and electronics manufacturing, food & beverage, pharmaceutical and laboratory nitrogen production.
  • When to Choose Membrane? Consider membrane generators when energy efficiency and cost-effectiveness take precedence over the highest nitrogen purity levels. Membrane systems are ideal for industries like marine, mining, oil & gas. It also includes applications such as inerting chemical products and flammable liquid, preventing dust explosions, central heating stations and metal 3D printing. Their ability to provide reliable, on-demand nitrogen with lower energy consumption makes them a practical choice for high-volume applications.

Conclusion

In summary, the choice between PSA and Membrane Nitrogen Generators depends on your specific application needs. Understanding these technical aspects will help you to select the optimal nitrogen generation technology for your industrial needs.

How Gas Generation Australia Can Help?

At Gas Generation Australia, we are committed to improving industrial processes through state-of-the-art onsite nitrogen generator systems. We provide cost-efficient solutions to ensure a dependable and consistent nitrogen gas supply customised to meet your specific industrial needs.

Making the switch to an onsite nitrogen generator is a strategic decision aimed at enhancing operational efficiency, safety, and sustainability. Gas Generation Australia is your ideal partner in this transition, offering cutting-edge solutions and expert support every step of the way. Contact us to find out more today!

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